全文获取类型
收费全文 | 87099篇 |
免费 | 8611篇 |
国内免费 | 9804篇 |
专业分类
化学 | 52449篇 |
晶体学 | 2143篇 |
力学 | 9230篇 |
综合类 | 1168篇 |
数学 | 17027篇 |
物理学 | 23497篇 |
出版年
2024年 | 102篇 |
2023年 | 720篇 |
2022年 | 1192篇 |
2021年 | 2288篇 |
2020年 | 2232篇 |
2019年 | 2116篇 |
2018年 | 1783篇 |
2017年 | 2199篇 |
2016年 | 2836篇 |
2015年 | 2694篇 |
2014年 | 3636篇 |
2013年 | 5960篇 |
2012年 | 5342篇 |
2011年 | 4634篇 |
2010年 | 4106篇 |
2009年 | 5103篇 |
2008年 | 5414篇 |
2007年 | 5730篇 |
2006年 | 4965篇 |
2005年 | 4248篇 |
2004年 | 4003篇 |
2003年 | 3770篇 |
2002年 | 6038篇 |
2001年 | 3184篇 |
2000年 | 2265篇 |
1999年 | 1966篇 |
1998年 | 1752篇 |
1997年 | 1514篇 |
1996年 | 1476篇 |
1995年 | 1382篇 |
1994年 | 1237篇 |
1993年 | 1108篇 |
1992年 | 1115篇 |
1991年 | 746篇 |
1990年 | 624篇 |
1989年 | 439篇 |
1988年 | 452篇 |
1987年 | 350篇 |
1986年 | 331篇 |
1985年 | 476篇 |
1984年 | 358篇 |
1983年 | 217篇 |
1982年 | 377篇 |
1981年 | 544篇 |
1980年 | 478篇 |
1979年 | 523篇 |
1978年 | 422篇 |
1977年 | 318篇 |
1976年 | 267篇 |
1973年 | 165篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
41.
Given two graphs and , a graph is -free if it contains no induced subgraph isomorphic to or . Let and be the path on vertices and the cycle on vertices, respectively. In this paper we show that for any -free graph it holds that , where and are the chromatic number and clique number of , respectively. Our bound is attained by several graphs, for instance, the 5-cycle, the Petersen graph, the Petersen graph with an additional universal vertex, and all -critical -free graphs other than (see Hell and Huang [Discrete Appl. Math. 216 (2017), pp. 211–232]). The new result unifies previously known results on the existence of linear -binding functions for several graph classes. Our proof is based on a novel structure theorem on -free graphs that do not contain clique cutsets. Using this structure theorem we also design a polynomial time -approximation algorithm for coloring -free graphs. Our algorithm computes a coloring with colors for any -free graph in time. 相似文献
42.
43.
44.
The electrochemical behavior of austenitic stainless steel (Type 304) in 3 M sulfuric acid with 3.5% recrystallized sodium chloride at specific concentrations of butan-1-ol was investigated with the aid of potentiodynamic polarization, open circuit measurement and weight loss technique. Butan-1-ol effectively inhibited the steel corrosion with a maximum inhibition efficiency of 78.7% from weight-loss analysis and 80.9% from potentiodynamic polarization test at highest concentration studied. Adsorption of the compound obeyed the Freundlich isotherm. Thermodynamic calculations reveal physiochemical interactions and spontaneous adsorption mechanism. Surface characterizations showed the absence of corrosion products and topographic modifications of the steel. Statistical analysis depicts the overwhelming influence and statistical significance of inhibitor concentration on the inhibition performance. 相似文献
45.
Gunasekaran Balamurugan Sundarraman Balaji Rengan Ramesh Nattamai S.P. Bhuvanesh 《应用有机金属化学》2019,33(1)
A panel of six new arene Ru (II)‐NHC complexes 2a‐f , (NHC = 1,3‐diethyl‐(5,6‐dimethyl)benzimidazolin‐2‐ylidene 1a , 1,3‐dicyclohexylmethyl‐(5,6‐dimethyl)benzimidazolin‐2‐ylidene 1b and 1,3‐dibenzyl‐(5,6‐dimethyl)benzimidazolin‐2‐ylidene 1c ) were synthesized from the transmetallation reaction of Ag‐NHC with [(η6‐arene)RuCl2]2 and characterized. The ruthenium (II)‐NHC complexes 2a‐f were developed as effective catalysts for α‐alkylation of ketones and synthesis of bioactive quinoline using primary/amino alcohols as coupling partners respectively. The reactions were performed with 0.5 mol% catalyst load in 8 h under aerobic condition and the maximum yield was up to 96%. Besides, the different alkyl wingtips on NHC and arene moieties were studied to differentiate the catalytic robustness of the complexes in the transformations. 相似文献
46.
建立了一种细胞趋硬性迁移的理论模型和有限元分析框架,为连续变刚度人工基质的试验设计提供理论依据。考虑了细胞体的黏弹性属性,以及细胞与基质间的配受体动态反应过程,并以配受体合成时间为时间步长,将细胞运动方程化为静力学形式进行求解。对有限元过程提出一种动约束,便于消除其结构矩阵的奇异性。结果表明,模型能够模拟黏着斑内部力的快速波动现象,细胞的运动速度与观测数据一致,可有效模拟20,h以上的长时程问题。 相似文献
47.
Pierre Thureau Simone Sturniolo Miri Zilka Fabio Ziarelli Stéphane Viel Jonathan R. Yates Giulia Mollica 《Magnetic resonance in chemistry : MRC》2019,57(5):256-264
Structure determination of functional organic compounds remains a formidable challenge when the sample exists as a powder. Nuclear magnetic resonance crystallography approaches based on the comparison of experimental and Density Functional Theory (DFT)-computed 1H chemical shifts have already demonstrated great potential for structure determination of organic powders, but limitations still persist. In this study, we discuss the possibility of using 13C-13C dipolar couplings quantified on powdered theophylline at natural isotopic abundance with the help of dynamic nuclear polarization, to realize a DFT-free, rapid screening of a pool of structures predicted by ab initio random structure search. We show that although 13C-13C dipolar couplings can identify structures possessing long range structural motifs and unit cell parameters close to those of the true structure, it must be complemented with other data to recover information about the presence and the chemical nature of the supramolecular interactions. 相似文献
48.
49.
Dr. Alyssa F. Schneider Prof. Michael A. Brook 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(67):15367-15374
Arylsilicones are widely exploited for their thermal and optical properties. The creation of phenylsilicone elastomers with specific physical properties is typically done by a “one-off” formulation and test process. Herein, it is demonstrated that high-throughput synthesis methods can be used to rapidly prepare a series of arylsilicone elastomers and then the relative impact of different aryl groups on their physical properties is assessed. Aromatic groups were incorporated into polydimethylsiloxane (PDMS) elastomers by exploiting the relative reactivity of different functional groups in the Piers–Rubinsztajn reaction. To analyze trends in the silicone mechanical properties as a function of increasing aryl concentration—structure/property relationships—libraries of elastomers were both quickly synthesized and characterized by using high-throughput suites starting from low viscosity silicone oils/monomers in 96-well plates. Liquid handling parameters were optimized to effectively work with the silicones. Incorporating aryl instead of alkyl crosslinkers into the PDMS backbone increased the silicone elastomer modulus by approximately 50 % (at a crosslink density of 6 %); elastomers prepared with an aromatic crosslinker with three contact points led to much higher moduli compared with those with one contact point at the same crosslink density. When located at precise rather than random points on the silicone chains, diphenylsilicones had lower moduli than analogous monophenylsilicones. 相似文献
50.
Iain D. H. Oswald 《Acta Crystallographica. Section C, Structural Chemistry》2019,75(8):1021-1022
A new crystalline form of αβ‐d ‐lactose prepared by oven drying a concentrated aqueous solution of d ‐lactose is a lesson in the power of observation and the rigorous analysis of powder samples. 相似文献